一水合二水合硼酸锂锰（II）磷酸盐
Lithium manganese(II) diaqua-boro-phosphate monohydrate.
作者信息
Zhuang Rong-Chuan, Chen Xue-Yun, Mi Jin-Xiao
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 5;64(Pt 8):i46. doi: 10.1107/S1600536808018898.
Abstract
The title compound, LiMn(H(2)O)(2)[BP(2)O(8)]·H(2)O, is built up of an open framework of helical borophosphate ribbons inter-connected by MnO(4)(H(2)O)(2) octa-hedra, forming one-dimensional channels along [001] occupied by Li(+) cations and disordered H(2)O mol-ecules (site occupancy 0.5). The Li cations reside in two partially occupied sites [occupancies = 0.42 (3) and 0.289 (13)] near the helices.
摘要
标题化合物LiMn(H₂O)₂[BP₂O₈]·H₂O由螺旋状硼磷酸盐带的开放框架构成，这些带通过MnO₄(H₂O)₂八面体相互连接，沿[001]方向形成一维通道，通道中存在Li⁺阳离子和无序的H₂O分子（占据率为0.5）。Li阳离子位于螺旋附近的两个部分占据的位置[占据率分别为0.42 (3)和0.289 (13)]。
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