• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

一水合二水合硼酸锂锰（II）磷酸盐

Lithium manganese(II) diaqua-boro-phosphate monohydrate.

作者信息

Zhuang Rong-Chuan, Chen Xue-Yun, Mi Jin-Xiao

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 5;64(Pt 8):i46. doi: 10.1107/S1600536808018898.

DOI:10.1107/S1600536808018898
PMID:21202989
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2961901/
Abstract

The title compound, LiMn(H(2)O)(2)[BP(2)O(8)]·H(2)O, is built up of an open framework of helical borophosphate ribbons inter-connected by MnO(4)(H(2)O)(2) octa-hedra, forming one-dimensional channels along [001] occupied by Li(+) cations and disordered H(2)O mol-ecules (site occupancy 0.5). The Li cations reside in two partially occupied sites [occupancies = 0.42 (3) and 0.289 (13)] near the helices.

摘要

标题化合物LiMn(H₂O)₂[BP₂O₈]·H₂O由螺旋状硼磷酸盐带的开放框架构成，这些带通过MnO₄(H₂O)₂八面体相互连接，沿[001]方向形成一维通道，通道中存在Li⁺阳离子和无序的H₂O分子（占据率为0.5）。Li阳离子位于螺旋附近的两个部分占据的位置[占据率分别为0.42 (3)和0.289 (13)]。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd4e/2961901/a5932fdddbe8/e-64-00i46-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd4e/2961901/eb85652b0b41/e-64-00i46-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd4e/2961901/9baa2bd583a3/e-64-00i46-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd4e/2961901/a5932fdddbe8/e-64-00i46-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd4e/2961901/eb85652b0b41/e-64-00i46-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd4e/2961901/9baa2bd583a3/e-64-00i46-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd4e/2961901/a5932fdddbe8/e-64-00i46-fig3.jpg

相似文献

1
Lithium manganese(II) diaqua-boro-phosphate monohydrate.一水合二水合硼酸锂锰（II）磷酸盐
Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 5;64(Pt 8):i46. doi: 10.1107/S1600536808018898.
2
Lithium diaqua-nickel(II) catena-borodiphosphate(V) monohydrate.一水合二水合镍（II）链状硼二磷酸（V）锂
Acta Crystallogr Sect E Struct Rep Online. 2009 May 7;65(Pt 6):i42. doi: 10.1107/S1600536809014652.
3
Lithium diaqua-magnesium catena-borodiphosphate(V) monohydrate, LiMg(H(2)O)(2)[BP(2)O(8)]·H(2)O, at 173 K.一水合二水合锂-镁链状焦磷酸硼(V)，LiMg(H₂O)₂[BP₂O₈]·H₂O，温度为173K 。
Acta Crystallogr Sect E Struct Rep Online. 2008 May 24;64(Pt 6):i39-i40. doi: 10.1107/S160053680801516X.
4
Silver(I) diaqua-magnesium catena-borodiphosphate(V) monohydrate, AgMg(H(2)O)(2)[BP(2)O(8)]·H(2)O.一水合二水合银（I）-链状硼酸二磷酸（V）镁，AgMg(H₂O)₂[BP₂O₈]·H₂O
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):i39. doi: 10.1107/S1600536811019477. Epub 2011 May 28.
5
Silver(I) diaqua-nickel(II) catena-borodiphosphate(V) hydrate, (Ag(0.57)Ni(0.22))Ni(H(2)O)(2)[BP(2)O(8)]·0.67H(2)O.二水合二磷酸银（I）-镍（II）链状水合物，(Ag(0.57)Ni(0.22))Ni(H₂O)₂[BP₂O₈]·0.67H₂O
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):i44. doi: 10.1107/S160053681102962X. Epub 2011 Jul 30.
6
Silver diaquacobalt(II) catena-borodiphosphate(V) hydrate, (Ag(0.79)Co(0.11))Co(H(2)O)(2)[BP(2)O(8)]·0.67H(2)O.水合二水合钴（II）链状硼二磷酸（V）银盐，(Ag(0.79)Co(0.11))Co(H₂O)₂[BP₂O₈]·0.67H₂O
Acta Crystallogr Sect E Struct Rep Online. 2012 Jan;68(Pt 1):i3-i4. doi: 10.1107/S1600536811052020. Epub 2011 Dec 7.
7
Na(5)(NH(4))Mn(3)[B(9)P(6)O(33)(OH)(3)]·1.5H(2)O.钠（5）（铵）锰（3）[硼（9）磷（6）氧（33）氢氧根（3）]·1.5水
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 22;64(Pt 12):i82-i83. doi: 10.1107/S1600536808037884.
8
KCo(H2O)2BP2O8·0.48H2O and K0.17Ca0.42Co(H2O)2BP2O8·H2O: two cobalt borophosphates with helical ribbons and disordered (K,Ca)/H2O schemes.
Acta Crystallogr C. 2012 Aug;68(Pt 8):i55-i59. doi: 10.1107/S0108270112030284. Epub 2012 Jul 25.
9
Wyllieite-type Ag(1.09)Mn(3.46)(AsO(4))(3).威利石型Ag(1.09)Mn(3.46)(AsO(4))(3)
Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 1;68(Pt 6):i40-i41. doi: 10.1107/S1600536812018843. Epub 2012 May 2.
10
Crystal structure of magnesium copper(II) bis-[orthophosphate(V)] monohydrate.一水合磷酸镁铜（II）双[正磷酸（V）]的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Jan 1;71(Pt 1):55-7. doi: 10.1107/S2056989014026930.

本文引用的文献

1
Lithium diaqua-magnesium catena-borodiphosphate(V) monohydrate, LiMg(H(2)O)(2)[BP(2)O(8)]·H(2)O, at 173 K.一水合二水合锂-镁链状焦磷酸硼(V)，LiMg(H₂O)₂[BP₂O₈]·H₂O，温度为173K 。
Acta Crystallogr Sect E Struct Rep Online. 2008 May 24;64(Pt 6):i39-i40. doi: 10.1107/S160053680801516X.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.