1-[(Z)-2-氰基-2-(2-吡啶基)乙烯基]-二茂铁
1-[(Z)-2-Cyano-2-(2-pyrid-yl)vin-yl]-ferrocene.
作者信息
Fu Xue-Qun, Wang Wei
机构信息
Ordered Matter Science Research Center, Southeast University, Nanjing 210096, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 19;64(Pt 8):m1043. doi: 10.1107/S1600536808021843.
Abstract
In the title compound, [Fe(C(5)H(5))(C(13)H(9)N(2))], the dihedral angle between the substituted cyclo-penta-dienyl plane and the plane of the pyridine ring is 8.43 (14)°. The double bond adopts a Z configuration. In the crystal structure, weak C-H⋯N inter-actions link the molecules into a zigzag chain. A weak intramolecular C-H⋯N hydrogen bond is also present.
摘要
在标题化合物[Fe(C₅H₅)(C₁₃H₉N₂)]中，取代的环戊二烯基平面与吡啶环平面之间的二面角为8.43 (14)°。双键呈Z构型。在晶体结构中，弱的C—H⋯N相互作用将分子连接成锯齿链。还存在一个弱的分子内C—H⋯N氢键。
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