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链状聚[[三甲基锡(IV)]-μ-[(E)-2-甲基-3-(3-甲基苯基)丙烯酸根-κO:O']]

catena-Poly[[trimethyl-tin(IV)]-μ-[(E)-2-methyl-3-(3-methyl-phen-yl)acrylato-κO:O']].

作者信息

Muhammad Niaz, Tahir M Nawaz, Ali Saqib

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 5;64(Pt 8):m978. doi: 10.1107/S1600536808019533.

DOI:10.1107/S1600536808019533
PMID:21203077
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2961908/
Abstract

The title trimethyl-tin(IV) carboxyl-ate, Sn(CH(3))(3)(C(11)H(11)O(2)), is a carboxyl-ate-bridged polymer in which the Sn atom exists in a trans-C(3)SnO(2) trigonal bipyramidal coordination. One Sn-O bond is a covalent bond [2.114 (2) Å], whereas the other is a dative bond [2.607 (2) Å]. The polymeric chain propagates along the b axis of the monoclinic unit cell.

摘要

标题化合物三甲基锡（IV）羧酸盐，Sn(CH(3))(3)(C(11)H(11)O(2))，是一种羧酸盐桥连聚合物，其中Sn原子以反式-C(3)SnO(2)三角双锥配位形式存在。一条Sn-O键为共价键[2.114 (2) Å]，而另一条为配位键[2.607 (2) Å]。聚合物链沿单斜晶胞的b轴延伸。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/93d2/2961908/654aa1e5c2bd/e-64-0m978-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/93d2/2961908/7023227ddfcd/e-64-0m978-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/93d2/2961908/654aa1e5c2bd/e-64-0m978-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/93d2/2961908/7023227ddfcd/e-64-0m978-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/93d2/2961908/654aa1e5c2bd/e-64-0m978-fig2.jpg

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