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链状聚[[(硝酸根-κO,O')银(I)]-μ-1,2-双(二苯基膦基)乙烷-κP:P']

catena-Poly[[(nitrato-κO,O')silver(I)]-μ-1,2-bis-(diphenyl-phosphino)ethane-κP:P'].

作者信息

Wang Xing-Cong, Wu Yan-Li, You Xiu-Li

机构信息

Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 5;64(Pt 8):m981. doi: 10.1107/S1600536808019442.

DOI:10.1107/S1600536808019442
PMID:21203079
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2961910/
Abstract

In the title chain compound, Ag(NO(3))(C(26)H(24)P(2)), the bis-(diphenyl-phosphino)ethane (dppe) units link the Ag(+) ions into chains along [001]. A nitrate anion is coordinated to the Ag atom. There is a centre of symmetry at the mid-point of the ethane C-C bond and a twofold rotation axis passes through the Ag, N and terminal O atoms. Each Ag atom is four-coordinated in a distorted tetra-hedral geometry by two O atoms of the nitrate anion and two P atoms of dppe ligands. The two aromatic rings are oriented at a dihedral angle of 73.77 (3)°.

摘要

在标题链状化合物[Ag(NO₃)(C₂₆H₂₄P₂)]ₙ中，双（二苯基膦基）乙烷（dppe）单元沿着[001]方向将Ag⁺离子连接成链。一个硝酸根阴离子与Ag原子配位。在乙烷C-C键的中点处有一个对称中心，并且有一个二重旋转轴穿过Ag、N和末端O原子。每个Ag原子通过硝酸根阴离子的两个O原子和dppe配体的两个P原子以扭曲的四面体几何构型进行四配位。两个芳环以73.77 (3)°的二面角取向。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/94a3/2961910/09dbcebcec41/e-64-0m981-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/94a3/2961910/8bb8928b02f7/e-64-0m981-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/94a3/2961910/09dbcebcec41/e-64-0m981-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/94a3/2961910/8bb8928b02f7/e-64-0m981-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/94a3/2961910/09dbcebcec41/e-64-0m981-fig2.jpg

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