Joint Laboratory of Green Synthetic Chemistry, Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China.
Chem Commun (Camb). 2011 Feb 21;47(7):2158-60. doi: 10.1039/c0cc04739b. Epub 2011 Jan 5.
A broad range of readily accessible N-sulfonyl imines undergo olefination reaction with nonstabilized phosphonium ylides under mild conditions to afford an array of both Z- and E-isomers of 1,2-disubstituted alkenes, allylic alcohols, and allylic amines in good yields and with greater than 99 : 1 stereoselectivity.
一系列广泛易得的 N-磺酰亚胺在温和条件下与非稳定膦叶立德发生烯烃化反应，以高收率和大于 99:1 的立体选择性得到一系列 Z-和 E-构型的 1,2-二取代烯烃、烯丙醇和烯丙胺。
