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通过剥离氧化石墨的铁还原法制备石墨烯纳米片。

Facile synthesis of graphene nanosheets via Fe reduction of exfoliated graphite oxide.

机构信息

Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, China.

出版信息

ACS Nano. 2011 Jan 25;5(1):191-8. doi: 10.1021/nn102339t. Epub 2010 Dec 7.

Abstract

The synthesis of graphene nanosheets from graphite oxide typically involves harmful chemical reductants that are undesirable for most practical applications of graphene. Here, we demonstrate a green and facile approach to the synthesis of graphene nanosheets based on Fe reduction of exfoliated graphite oxide, resulting in a substantial removal of oxygen functionalities of the graphite oxide. More interestingly, the resulting graphene nanosheets with residual Fe show a high adsorption capacity of 111.62 mg/g for methylene blue at room temperature, as well as easy magnetic separation from the solution. This approach offers a potential for cost-effective, environmentally friendly, and large-scale production of graphene nanosheets.

摘要

从氧化石墨合成石墨烯纳米片通常涉及使用有害的化学还原剂,这对于大多数石墨烯的实际应用来说是不可取的。在这里,我们展示了一种基于剥离氧化石墨的铁还原的绿色简便的合成石墨烯纳米片的方法,从而大量去除了氧化石墨的含氧官能团。更有趣的是,所得的具有残留铁的石墨烯纳米片在室温下对亚甲基蓝表现出高的吸附容量为 111.62mg/g,并且易于从溶液中磁性分离。这种方法为具有成本效益、环保和大规模生产石墨烯纳米片提供了一种可能。

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