乙烯基二氮磷作为季铵取代吲哚啉和环戊烯的前体。
Vinyl diazophosphonates as precursors to quaternary substituted indolines and cyclopentenes.
机构信息
Department of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112, USA.
出版信息
Org Lett. 2011 Feb 18;13(4):700-2. doi: 10.1021/ol102931n. Epub 2011 Jan 14.
PMID:21235249
Abstract
Vinyl diazophosphonates can be stereoselectively synthesized and, depending upon their substitution pattern, undergo intramolecular C-H insertion reactions or sulfonium ylide rearrangements when exposed to Rh(2)(OAc)(4).
摘要
乙烯基二氮磷氧化物可以进行立体选择性合成，并且当暴露于 Rh(2)(OAc)(4)时，根据其取代模式，会发生分子内 C-H 插入反应或锍叶立德重排反应。
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