由于胶囊内缺乏自由空间，限制了其旋转，从而导致产物选择性：水溶性有机胶囊内环己基苯酮的光化学反应。
Restricted rotation due to the lack of free space within a capsule translates into product selectivity: photochemistry of cyclohexyl phenyl ketones within a water-soluble organic capsule.
机构信息
Department of Chemistry, University of Miami, Coral Gables, FL 33124, USA.
出版信息
Chem Commun (Camb). 2011 Mar 14;47(10):2841-3. doi: 10.1039/c0cc05337f. Epub 2011 Jan 21.
PMID:21253635
Abstract
The rotational mobility of organic guest molecules when included within a confined capsule is restricted and this feature could be translated into product selectivity as established with the photochemical behavior of cyclohexyl phenyl ketones.
摘要
当有机客体分子被包含在受限胶囊内时，其旋转迁移性受到限制，并且这一特性可以转化为产物选择性，这已通过环己基苯基酮的光化学反应行为得到证实。
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