Environmental Research Laboratory, Kinki University, 3-4-1, Kowakae, Higashi-Osaka, Osaka, 577-8502, Japan.
Chem Commun (Camb). 2011 Mar 21;47(11):3230-2. doi: 10.1039/c0cc03047c. Epub 2011 Jan 24.
Catalytic activity of gold nanoparticle (NP)-loaded metal oxide semiconductors (Au/MOs) for H(2)O(2) decomposition and chemoselective oxidation of cinnamyl alcohol to cinnamaldehyde strongly depends on both the kind of the MO-supports and the Au particle size, and Au/SrTiO(3) exhibits an extraordinary high level of activity for the H(2)O(2) decomposition exceeding that of Pt/TiO(2).
负载金纳米颗粒(Au/NPs)的金属氧化物半导体(Au/MOs)对 H(2)O(2)分解和肉桂醇选择性氧化为肉桂醛的催化活性强烈依赖于 MO 载体的种类和 Au 颗粒尺寸,而 Au/SrTiO(3) 对 H(2)O(2)分解的活性极高,超过了 Pt/TiO(2)。