Departamento de Química Inorgánica, UCM, Facultad de Químicas, Universidad Complutense, Madrid, Spain.
Chemistry. 2011 Feb 25;17(9):2709-15. doi: 10.1002/chem.201002080. Epub 2011 Jan 24.
Resistance measurements indicate the presence of magnetoresistance in the La(0.5)Sr(0.5)MnO(2.5) brownmillerite related compound. An 80 % of magnetoresistance is found at 75 K. In spite of the partial break-up occurring at the 3D network of octahedra sharing corners, characteristic of the full oxygen content perovskite phase, the oxygen deficient compound exhibits complex magnetic and electric properties. Such behavior can be explained on the basis of ferromagnetic and metallic clusters randomly distributed at the octahedral layers separated from each other by an insulating antiferromagnetic matrix. AC susceptibility measurements suggest spin glass behavior at low temperature as a consequence of the competition between different magnetic interactions.
电阻测量表明,La(0.5)Sr(0.5)MnO(2.5) 褐锰矿相关化合物存在磁电阻。在 75 K 时发现了 80%的磁电阻。尽管在八面体共享角的 3D 网络中发生了部分断裂,这是全氧含量钙钛矿相的特征,但缺氧化合物表现出复杂的磁电性质。这种行为可以基于随机分布在由绝缘反铁磁基质隔开的八面体层中的铁磁和金属簇来解释。交流磁化率测量表明,由于不同磁相互作用之间的竞争,低温下存在自旋玻璃行为。