2-碘代安息香酸——一种简单的氧化剂，具有令人眼花缭乱的潜在应用。

2-Iodoxybenzoic acid--a simple oxidant with a dazzling array of potential applications.

机构信息

Department Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching, Germany.

出版信息

Angew Chem Int Ed Engl. 2011 Feb 11;50(7):1524-52. doi: 10.1002/anie.201000873. Epub 2011 Jan 26.

DOI:10.1002/anie.201000873

Abstract

Since its discovery by Christoph Hartmann and Victor Meyer in 1893, 2-iodoxybenzoic acid (IBX) has emerged as a rather ubiquitous oxidant for organic synthesis. The past decade has seen the development of a large variety of applications that go far beyond the simple oxidation of alcohols. This Review is concerned with the synthetic potential of IBX, with particular emphasis on uncommon reactivity patterns and novel fields of application.

摘要

自 1893 年 Christoph Hartmann 和 Victor Meyer 发现以来，2-碘氧基苯甲酸（IBX）已成为一种相当普遍的有机合成氧化剂。在过去的十年中，已经开发出了各种各样的应用，远远超出了简单的醇氧化。本文综述了 IBX 的合成潜力，特别强调了不常见的反应模式和新的应用领域。