Yusubov Mekhman S, Soldatova Natalia S, Postnikov Pavel S, Valiev Rashid R, Yoshimura Akira, Wirth Thomas, Nemykin Victor N, Zhdankin Viktor V
The Tomsk Polytechnic University, 634050 Tomsk, Russia.
School of Chemistry, Cardiff University, Park Place, Cardiff, CF10 3AT, UK.
Chem Commun (Camb). 2019 Jul 11;55(54):7760-7763. doi: 10.1039/c9cc04203b. Epub 2019 Jun 18.
A ditriflate derivative of 2-iodoxybenzoic acid (IBX) was prepared by the reaction of IBX with trifluoromethanesulfonic acid and characterized by single crystal X-ray crystallography. IBX-ditriflate is the most powerful oxidant in a series of structurally similar IBX derivatives which is best illustrated by its ability to readily oxidize hydrocarbons and the oxidation resistant polyfluoroalcohols.
通过2-碘酰基苯甲酸（IBX）与三氟甲磺酸反应制备了一种IBX的二（三氟甲磺酸盐）衍生物，并通过单晶X射线晶体学对其进行了表征。在一系列结构相似的IBX衍生物中，IBX-二（三氟甲磺酸盐）是最强的氧化剂，这一点最能通过其易于氧化烃类和耐氧化的多氟醇的能力体现出来。
