糖衍生的硝基亚烯与环戊二烯之间的 Diels-Alder 反应的实验和理论研究。
Experimental and theoretical study of a Diels-Alder reaction between a sugar-derived nitroalkene and cyclopentadiene.
机构信息
Instituto de Química de Rosario, Facultad de Ciencias Bioquímicas y Farmacéuticas, Universidad Nacional de Rosario-CONICET, Suipacha 531, Rosario, Argentina.
出版信息
Carbohydr Res. 2011 Mar 1;346(4):460-4. doi: 10.1016/j.carres.2010.12.006. Epub 2010 Dec 13.
PMID:21272863
Abstract
The Diels-Alder reaction of a pyranose-derived nitroalkene 1 with cyclopentadiene is described, and the unexpected facial selectivity of the cycloaddition is analyzed by a computational study.
摘要
描述了吡喃糖衍生的硝基烯烃 1 与环戊二烯的 Diels-Alder 反应，并通过计算研究分析了环加成的意外面选择性。
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