Department of Chemistry and Center for Catalysis Research and Innovation, University of Ottawa, Ottawa, ON, K1N 6N5 Canada.
Chem Commun (Camb). 2011 Mar 21;47(11):3177-9. doi: 10.1039/c0cc05408a. Epub 2011 Jan 31.
Significant advantages result from combining the disparate hydrogen release pathways for ammonia-borane (AB) dehydrogenation using ionic liquids (ILs) and transition metal catalysts. With the RuCl(2)(PMe(3))(4) catalyst precursor, AB dehydrogenation selectivity and extent are maximized in an IL with a moderately coordinating ethylsulfate anion.
采用离子液体（ILs）和过渡金属催化剂组合氨硼烷（AB）脱氢的不同氢释放途径可带来显著优势。使用 RuCl(2)(PMe(3))(4) 催化剂前体，在具有中等配位能力的乙基硫酸盐阴离子的 IL 中，AB 脱氢的选择性和程度达到最大。
