Beijing National Laboratory of Molecular Science, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, China.
Chem Soc Rev. 2011 Jun;40(6):3157-81. doi: 10.1039/c0cs00093k. Epub 2011 Jan 31.
Framework-structured weak ferromagnets are new rising stars in molecule-based magnetic materials. The framework structures are powerful carriers for long-range ordering of spins. And weak ferromagnetism due to spin canting is an effective approach for magnets because of its frequent occurrence and desired spontaneous magnetization as long as the canting angle γ is large enough. In this critical review, we provide an overview of the various framework-structured weak ferromagnets based on different grades of ligands (from mono-atom to three-atom-like ligands). Particular emphasis is given to the relationships between structural features and the properties, rational employment of the ligands, and weak ferromagnetic strategies for molecule-based magnets with exciting properties and applications (273 references).
框架结构弱铁磁体是分子基磁性材料中新兴的佼佼者。框架结构是自旋长程有序的强大载体。而由于自旋倾斜导致的弱铁磁性是一种有效的磁铁方法，因为只要倾斜角 γ 足够大，就会出现自发磁化。在这篇评论中，我们概述了基于不同配体（从单原子到三原子类似配体）的各种框架结构弱铁磁体。特别强调了结构特征与性能之间的关系、配体的合理应用以及具有令人兴奋的性质和应用的分子基磁铁的弱铁磁策略（273 篇参考文献）。
