School of Chemistry & Material Science, Shanxi Normal University, Linfen, Shanxi, P R China.
Dalton Trans. 2011 Mar 14;40(10):2092-8. doi: 10.1039/c0dt00979b. Epub 2011 Jan 31.
Single-crystal-to-single-crystal (SCSC) transformations have recently been found in some molecular magnets, which involve rearrangement or dynamic movement of molecular components of the crystals. Various stimuli such as guest removal, guest exchange, ligand exchange as well as redox reactions may induce SCSC transformations. To date, only a few molecular magnets are known to exhibit SCSC transformations, which often show high-dimensional robust structures. This review mainly focuses on magnetic complexes that are robust enough to experience SCSC transformations and show magnetic changes induced by solvents in due course. This contribution is organized according to the means of solvent treatment of molecular magnets, aiming at revealing magneto-structural correlation in such SCSC transformations.
单晶到单晶（SCSC）转变最近在一些分子磁体中被发现，涉及晶体中分子组件的重排或动态运动。各种刺激，如客体去除、客体交换、配体交换以及氧化还原反应，都可能引发 SCSC 转变。迄今为止，只有少数分子磁体被发现具有 SCSC 转变，这些转变通常表现出高维的坚固结构。这篇综述主要关注那些坚固到足以经历 SCSC 转变并在适当的时候显示溶剂诱导的磁变化的磁配合物。这一贡献是根据分子磁体的溶剂处理手段来组织的，旨在揭示这种 SCSC 转变中的磁结构相关性。
