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Cu 衬底上负载 CuO 纳米结构作为集成电极用于高可逆锂存储。

CuO nanostructures supported on Cu substrate as integrated electrodes for highly reversible lithium storage.

机构信息

School of Chemical and Biomedical Engineering, Nanyang Technological University, 70 Nanyang Drive, 637457, Singapore.

出版信息

Nanoscale. 2011 Apr;3(4):1618-23. doi: 10.1039/c0nr00827c. Epub 2011 Feb 1.

Abstract

Arrays of CuO nanostructures, including nanorods and nanosheets, supported on a Cu substrate have been rationally fabricated from their morphology-controlled Cu(2)(OH)(3)NO(3) precursors by thermal annealing. The as-prepared CuO samples can be directly used as integrated electrodes for lithium-ion batteries without the addition of other ancillary materials such as carbon black or a binder to enhance electrode conductivity and cycling stability. The unique nanostructural features endower them excellent electrochemical performance as demonstrated by high capacities of 450-650 mAh g(-1) at 0.5-2 C and almost 100% capacity retention over 100 cycles after the second cycle.

摘要

已经通过热退火,从其形态可控的 Cu(2)(OH)(3)NO(3)前体中合理地制备了在 Cu 基底上的 CuO 纳米结构阵列,包括纳米棒和纳米片。无需添加其他辅助材料(如炭黑或粘结剂)来提高电极导电性和循环稳定性,所制备的 CuO 样品可以直接用作锂离子电池的集成电极。独特的纳米结构特征使它们具有出色的电化学性能,例如在 0.5-2 C 的电流密度下具有 450-650 mAh g(-1)的高容量,并且在第二次循环后经过 100 次循环后容量保持率几乎为 100%。

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