(+)-丹卡脂素 A 的不对称全合成。
Asymmetric total synthesis of (+)-danicalipin A.
机构信息
Graduate School of Pharmaceutical Sciences, Osaka University, Suita, Osaka, Japan.
出版信息
Org Lett. 2011 Mar 4;13(5):908-11. doi: 10.1021/ol1029518. Epub 2011 Feb 2.
PMID:21288044
Abstract
A convergent asymmetric total synthesis of (+)-danicalipin A is accomplished, in which two chlorinated fragments are stereoselectively joined by 1,3-dipolar coupling, leading to the confirmation of the absolute configuration of the natural product.
摘要
（+）-丹卡林 A 的收敛不对称全合成得以实现，其中两个氯化片段通过 1,3-偶极环加成立体选择性地连接，从而确定了天然产物的绝对构型。
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