Department of Chemistry, Brandeis University, 415 South Street, Waltham, MA 02454, USA.
Chem Commun (Camb). 2011 Mar 28;47(12):3634-6. doi: 10.1039/c0cc05739h. Epub 2011 Feb 10.
The synthesis of a new pincer ligand containing a central cationic N-heterocyclic phosphenium donor is described. The electrophilic nature of this cationic ligand renders it non-innocent, and coordination of this ligand to a PtCl(2) fragment leads to chloride migration from Pt to the cationic phosphorus center.
描述了一种新型含中心阳离子 N-杂环膦烯供体的钳子配体的合成。这种阳离子配体的亲电性使其非中性，并且该配体与 PtCl(2)片段的配位导致氯离子从 Pt 迁移到阳离子磷中心。
