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可极化偶极子靶的电子俘获:俘获概率的数值和解析近似。

Electron capture by polarizable dipolar targets: numerical and analytically approximated capture probabilities.

机构信息

Schulich Faculty of Chemistry, Technion-Israel Institute of Technology Haifa, 32000, Israel.

出版信息

J Phys Chem A. 2011 Jun 30;115(25):6825-30. doi: 10.1021/jp110501n. Epub 2011 Feb 22.

Abstract

Numerically accurate and analytically approximated partial wave probabilities for the capture of a charged particle by a stationary polarizable dipole are presented over wide ranges of collision energies. The results facilitate the analysis of electron-molecule attachment in terms of capture rates, contributions from electron-phonon coupling, and kinetic properties when metastable anions are formed.

摘要

给出了在宽碰撞能范围内,对被固定可极化偶极子俘获的带电粒子的数值精确和解析近似的分波概率。这些结果有助于根据俘获率、电子-声子耦合的贡献以及形成亚稳态阴离子时的动力学性质,来分析电子-分子附着。

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