微波辅助合成具有 Fe4(OH)4 立方烷核的超顺磁十二核铁(III)配合物。
Microwave-assisted synthesis of a ferrimagnetic dodecanuclear iron(III) complex with a Fe4(OH)4 cubane core.
机构信息
State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, People's Republic of China.
出版信息
Inorg Chem. 2011 Mar 21;50(6):2067-9. doi: 10.1021/ic102411u. Epub 2011 Feb 22.
PMID:21341732
Abstract
The microwave-assisted reaction of Fe(ClO(4))(2) with NaN(3), NaO(2)CPh, and 1,3-di(2-pyridyl)-1,3-propanedione gave a ferrimagnetic dodecanuclear iron(III) complex that shows magnetization relaxation behavior.
摘要
采用微波辅助法，以 Fe(ClO4)2、NaN3、NaO2CPh 和 1,3-二(2-吡啶基)-1,3-丙烷二酮为反应物，得到了一种具有铁磁性质的十二核铁(III)配合物，该配合物表现出磁化弛豫行为。
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