A boronium ion with exceptional electrophilicity.
作者信息
Prokofjevs Aleksandrs, Kampf Jeff W, Vedejs Edwin
机构信息
Department of Chemistry, University of Michigan, 930 N. University Ave, Ann Arbor, MI 48109-1055, USA.
出版信息
Angew Chem Int Ed Engl. 2011 Feb 25;50(9):2098-101. doi: 10.1002/anie.201005663. Epub 2011 Jan 24.
Abstract
摘要
相似文献
1
A boronium ion with exceptional electrophilicity.一种具有异常亲电性的硼鎓离子。
Angew Chem Int Ed Engl. 2011 Feb 25;50(9):2098-101. doi: 10.1002/anie.201005663. Epub 2011 Jan 24.
2
Boracyclophanes: modulation of the σ/π character in boron-benzene interactions.硼环蕃：硼-苯相互作用中σ/π特性的调控
Angew Chem Int Ed Engl. 2013 Jul 29;52(31):8054-8. doi: 10.1002/anie.201303830. Epub 2013 Jun 20.
3
Spirocyclic boronium ions: precursors to persistent neutral radicals.螺环硼鎓离子：稳定中性自由基的前体。
Chem Commun (Camb). 2009 Sep 14(34):5147-9. doi: 10.1039/b911982e. Epub 2009 Jul 20.
4
The influence of fluorine position on the properties of fluorobenzoxaboroles.氟原子位置对氟代苯并硼恶唑性质的影响。
Bioorg Chem. 2015 Jun;60:130-5. doi: 10.1016/j.bioorg.2015.05.004. Epub 2015 May 14.
5
Novel binaphthyl-containing bi-nuclear boron complex with low concentration quenching effect for efficient organic light-emitting diodes.含联萘基的新型双核硼配合物，浓度猝灭效应低，用于高效有机发光二极管。
Chem Commun (Camb). 2010 Sep 21;46(35):6512-4. doi: 10.1039/c0cc01715a. Epub 2010 Aug 10.
6
Synthesis of sterically crowded polyarylated boron-dipyrromethenes.稠合多芳基取代硼二吡咯甲烷的合成。
J Org Chem. 2011 Oct 21;76(20):8466-71. doi: 10.1021/jo2010022. Epub 2011 Sep 23.
7
Calculated 11B-13C NMR chemical shift relationship in hypercoordinate methonium and boronium ions.超配位甲鎓离子和硼鎓离子中计算得到的11B - 13C NMR化学位移关系。
Proc Natl Acad Sci U S A. 1998 Jun 23;95(13):7257-9. doi: 10.1073/pnas.95.13.7257.
8
Total synthesis of (+)-oocydin A: application of the Suzuki-Miyaura cross-coupling of 1,1-dichloro-1-alkenes with 9-alkyl 9-BBN.(+)-卵孢霉素A的全合成：1,1-二氯-1-烯烃与9-烷基-9-硼双环[3.3.1]壬烷的铃木-宫浦交叉偶联反应的应用
Angew Chem Int Ed Engl. 2008;47(20):3762-5. doi: 10.1002/anie.200800585.
9
Boron-containing inhibitors of synthetases.含硼的合成酶抑制剂。
Chem Soc Rev. 2011 Aug;40(8):4279-85. doi: 10.1039/c0cs00131g. Epub 2011 Feb 7.
10
Boron-based phosphodiesterase inhibitors show novel binding of boron to PDE4 bimetal center.硼基磷酸二酯酶抑制剂显示出硼与 PDE4 双金属中心的新型结合。
FEBS Lett. 2012 Sep 21;586(19):3410-4. doi: 10.1016/j.febslet.2012.07.058. Epub 2012 Jul 25.
引用本文的文献
1
Ligand non-innocence and an unusual σ-bond metathesis step enables catalytic borylation using 9-borabicyclo-[3.3.1]-nonane.配体的非惰性以及一个不寻常的σ键复分解步骤使得能够使用9-硼双环[3.3.1]壬烷进行催化硼化反应。
Chem Sci. 2025 Apr 15. doi: 10.1039/d5sc02085a.
2
Regioselective access to B-N Lewis pair-functionalized anthracenes: mechanistic studies and optoelectronic properties.区域选择性合成硼-氮路易斯酸碱对功能化蒽：机理研究与光电性质
Chem Sci. 2025 Apr 2;16(18):8114-8124. doi: 10.1039/d5sc00597c. eCollection 2025 May 7.
3
Hydrogenolysis of Haloboranes: from Synthesis of Hydroboranes to Formal Hydroboration Reactions.卤硼烷的氢解反应：从硼烷的合成到形式硼氢化反应
Angew Chem Int Ed Engl. 2024 Dec 9;63(50):e202411468. doi: 10.1002/anie.202411468. Epub 2024 Oct 18.
4
Metal-free C-H Borylation and Hydroboration of Indoles.吲哚的无金属C-H硼化和硼氢化反应
ACS Omega. 2023 Oct 2;8(41):37623-37640. doi: 10.1021/acsomega.3c05071. eCollection 2023 Oct 17.
5
The Non-Ancillary Nature of Trimethylsilylamide Substituents in Boranes and Borinium Cations.硼烷和硼鎓阳离子中三甲基硅酰胺取代基的非辅助性质
Chemistry. 2022 May 11;28(27):e202200698. doi: 10.1002/chem.202200698. Epub 2022 Apr 1.
6
Enhanced N-directed electrophilic C-H borylation generates BN-[5]- and [6]helicenes with improved photophysical properties.增强的氮导向亲电碳-氢键硼化反应生成了具有改善光物理性质的BN-[5]螺烯和[6]螺烯。
Chem Sci. 2022 Jan 4;13(4):1136-1145. doi: 10.1039/d1sc06513k. eCollection 2022 Jan 26.
7
Efficient metal-free photochemical borylation of aryl halides under batch and continuous-flow conditions.在间歇和连续流动条件下芳基卤化物的高效无金属光化学硼化反应。
Chem Sci. 2016 Jun 1;7(6):3676-3680. doi: 10.1039/c5sc04521e. Epub 2016 Feb 1.
8
Metal-free borylative dearomatization of indoles: exploring the divergent reactivity of aminoborane C-H borylation catalysts.吲哚的无金属硼化去芳构化反应：探索氨基硼烷C-H硼化催化剂的不同反应活性
Chem Sci. 2018 May 7;9(22):5057-5063. doi: 10.1039/c8sc01093e. eCollection 2018 Jun 14.
9
A family of N-heterocyclic carbene-stabilized borenium ions for metal-free imine hydrogenation catalysis.用于无金属亚胺氢化催化的N-杂环卡宾稳定的硼正离子家族。
Chem Sci. 2015 Mar 1;6(3):2010-2015. doi: 10.1039/c4sc03675a. Epub 2015 Jan 26.
10
Use of -methyliminodiacetic acid boronate esters in suzuki-miyaura cross-coupling polymerizations of triarylamine and fluorene monomers.甲基亚氨基二乙酸硼酸酯在三芳基胺和芴单体的铃木-宫浦交叉偶联聚合反应中的应用。
J Polym Sci A Polym Chem. 2017 Sep 1;55(17):2798-2806. doi: 10.1002/pola.28682. Epub 2017 Jul 3.
本文引用的文献
1
C-H activation for the construction of C-B bonds.用于构建碳-硼键的碳-氢活化反应。
Chem Rev. 2010 Feb 10;110(2):890-931. doi: 10.1021/cr900206p.
2
Superelectrophilic intermediates in nitrogen-directed aromatic borylation.氮导向芳基硼化反应中的超亲电中间体。
J Am Chem Soc. 2009 Oct 21;131(41):14679-87. doi: 10.1021/ja905369n.
3
On the track of novel triel-stabilised silylaminoiminoborenes.追寻新型三乙胺稳定的硅氨基亚氨基硼烷
Chemistry. 2009;15(18):4602-9. doi: 10.1002/chem.200802669.
4
Borenium cations derived from BODIPY dyes.源自BODIPY染料的硼正离子。
Chem Commun (Camb). 2008 Oct 14(38):4593-5. doi: 10.1039/b808739c. Epub 2008 Jul 31.
5
B-H activation by frustrated Lewis pairs: borenium or boryl phosphonium cation?受阻路易斯酸碱对引发的B-H活化：硼正离子还是硼基鏻阳离子？
Chem Commun (Camb). 2008 Sep 28(36):4303-5. doi: 10.1039/b808348g. Epub 2008 Jul 16.
6
Covalent radii revisited.共价半径再探讨。
Dalton Trans. 2008 Jun 7(21):2832-8. doi: 10.1039/b801115j. Epub 2008 Apr 7.
7
Borinium, borenium, and boronium ions: synthesis, reactivity, and applications.硼鎓离子、硼正离子和硼鎓离子：合成、反应性及应用
Angew Chem Int Ed Engl. 2005 Aug 12;44(32):5016-36. doi: 10.1002/anie.200500402.
8
Exploiting isolobal relationships to create new ionic liquids: novel room-temperature ionic liquids based upon (N-alkylimidazole)(amine)BH2+"boronium" ions.利用等瓣关系制备新型离子液体：基于（N-烷基咪唑）（胺）BH₂⁺“硼鎓”离子的新型室温离子液体。
Chem Commun (Camb). 2005 Aug 7(29):3679-81. doi: 10.1039/b504631a. Epub 2005 Jun 16.
9
Oxygen-bridged borate anions from tris(pentafluorophenyl)borane: synthesis, NMR characterization, and reactivity.三（五氟苯基）硼烷衍生的氧桥连硼酸根阴离子：合成、核磁共振表征及反应活性
Inorg Chem. 2005 Jul 11;44(14):5030-41. doi: 10.1021/ic0502168.
10
Catalytic activities of Cu(II) complexes with nitrogen-chelating bidentate ligands in the coupling of imidazoles with arylboronic acids.
J Org Chem. 2001 Nov 16;66(23):7892-7. doi: 10.1021/jo010615u.
Zotero 插件