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(210)Pb 和近地表沉积物和间隙水中的成分数据表明巴西马卡帕亚马孙河口存在人为输入。

(210)Pb and composition data of near-surface sediments and interstitial waters evidencing anthropogenic inputs in Amazon River mouth, Macapá, Brazil.

机构信息

Universidade Federal do Amapá (UNIFAP), Campus Marco Zero, Rodovia Juscelino Kubitschek, km 2, CEP 68902-280, Macapá, Amapá, Brazil.

出版信息

J Environ Radioact. 2011 Apr;102(4):348-62. doi: 10.1016/j.jenvrad.2011.01.008. Epub 2011 Feb 25.

DOI:10.1016/j.jenvrad.2011.01.008
PMID:21353731
Abstract

Activity profiles of excess (210)Pb determined in three sediment cores from Amazon River mouth, Macapá city, Brazil, provided the evaluation of sedimentation rates, contributing to a better knowledge of the hydrological conditions in the site that is the capital of Amapá State and is drained by the waters of the huge Amazon River. Chemical data were also determined in the sediments, allowing identify signatures coupled to anthropogenic inputs held in the past in Amapá State. Significant direct relationships between LOI (loss on ignition) and organic matter were found for all sediments profiles. Silica was found to be inversely related to organic matter in the three profiles; its decrease accompanied an increase on the specific surface of the sediments. This relationship was confirmed by a great number of inverse significant correlations among silica and oxides Na(2)O, K(2)O, CaO, MgO, Al(2)O(3), P(2)O(5), Fe(2)O(3) and MnO. It was possible to identify the role of organic matter on adsorption of several oxides in the core sediments profiles. Apparent sediment mass accumulation rates corresponding to values between 450 and 2510 mg cm(-2)yr(-1) were obtained, and are compatible with the results of others studies. The (210)Pb activities in one sampling point suggested the occurrence of anthropogenic inputs related to the initial period of the mining activities conducted in Serra do Navio, Amapá State, for the commercialization of Mn ores. This was reinforced by the abrupt fluctuations in chemical data obtained for the sediments and composition of the interstitial waters occurring there. The Atlantic hurricane activity also appeared to affect the sedimentation rates in the area, as two different values were recorded in each profile.

摘要

从巴西马卡帕市亚马孙河口的三个沉积岩心测定的过剩 (210)Pb 活动剖面,评估了沉积速率,有助于更好地了解该地区的水文条件。该地区是阿马帕州的首府,由浩瀚的亚马孙河河水所滋养。沉积物中还测定了化学数据,可识别过去在阿马帕州存在的与人为投入有关的特征。所有沉积物剖面都发现了 LOI(烧失量)与有机质之间存在显著的直接关系。在三个剖面中都发现硅与有机质呈负相关;硅的减少伴随着沉积物比表面积的增加。这种关系得到了大量硅与氧化物 Na(2)O、K(2)O、CaO、MgO、Al(2)O(3)、P(2)O(5)、Fe(2)O(3) 和 MnO 之间反向显著相关性的证实。可以确定有机质在核心沉积物剖面中对几种氧化物吸附的作用。得到的表观沉积物质量累积速率介于 450 至 2510 mg cm(-2)yr(-1)之间,与其他研究的结果一致。一个采样点的 (210)Pb 活度表明存在与亚马孙州 Serra do Navio 的采矿活动初始阶段有关的人为投入,用于 Mn 矿石的商业化。这一点得到了沉积物中化学数据的突然波动以及该处间隙水组成的支持。大西洋飓风活动似乎也影响了该地区的沉积速率,因为每个剖面中都记录了两个不同的值。

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