School of Chemistry and Chemical Engineering, The QUILL Centre, Queen's University, Belfast BT9 5AG, UK.
J Phys Chem B. 2011 Mar 24;115(11):2574-81. doi: 10.1021/jp1120096. Epub 2011 Feb 28.
The electrochemistry of HgCl(2) and [Hg(NTf(2))(2)] (NTf(2)=bis-{(trifluoromethyl)sulfonyl}imide) has been studied in room temperature ionic liquids. It has been found that the cyclic voltammetry of Hg(II) is strongly dependent on a number of factors (e.g., concentration, anions present in the mixture, and nature of the working electrode) and differs from that found in other media. Depending on conditions, the cyclic voltammetry of Hg(II) can give rise to one, two, or four reduction peaks, whereas the reverse oxidative scans show two to four peaks. Diffuse reflectance UV-vis spectroscopy and X-ray powder diffraction have been used to aid the assignment of the voltammetric waves.
HgCl(2) 和 [Hg(NTf(2))(2)] (NTf(2)=双(三氟甲基磺酰)亚胺) 在室温离子液体中的电化学性质已经过研究。研究发现，Hg(II) 的循环伏安法强烈依赖于许多因素（例如浓度、混合物中存在的阴离子以及工作电极的性质），并且与在其他介质中发现的情况不同。根据条件的不同，Hg(II) 的循环伏安法可以产生一个、两个或四个还原峰，而反向氧化扫描则显示两个到四个峰。漫反射紫外-可见光谱和 X 射线粉末衍射已被用于辅助对伏安波的分配。
