School of Chemistry and Chemical Engineering, Liaocheng University, 252059 Liaocheng, People's Republic of China.
Inorg Chem. 2011 Apr 4;50(7):2705-7. doi: 10.1021/ic101622d. Epub 2011 Mar 3.
A novel enneanuclear manganese complex, [Mn(9)O(4)(Mesao)(6)(MeO)(3)(O(2)CMe)(3)(OH)(MeOH)(2)]·2.5DMF [1; Me-saoH(2) = 2-hydroxyphenylethanone oxime], was synthesized. The structure of 1 contains an unusual [Mn(9)O(4)] core with an unprecedented defective "supertetrahedron" topology based on two parallel, onset stacked 9-MC-3 and 15-MC-6 metallacrown subunits. Magnetic studies indicate that 1 behaves as a single-molecule magnet.
一种新型九核锰配合物，[Mn(9)O(4)(Mesao)(6)(MeO)(3)(O(2)CMe)(3)(OH)(MeOH)(2)]·2.5DMF [1; Me-saoH(2) = 2- 羟基苯乙酮肟]，被合成出来。1 的结构包含一个不寻常的[Mn(9)O(4)]核心，具有基于两个平行、起始堆叠的 9-MC-3 和 15-MC-6 金属冠亚基的前所未有的缺陷“超四面体”拓扑结构。磁性研究表明 1 表现为单分子磁体。
