Institute for Water Quality, Resource and Waste Management, Vienna University of Technology, Vienna, Austria.
Waste Manag Res. 2011 Oct;29(10 Suppl):3-12. doi: 10.1177/0734242X10394913. Epub 2011 Mar 7.
Thermal utilization of municipal solid waste and commercial wastes has become of increasing importance in European waste management. As waste materials are generally composed of fossil and biogenic materials, a part of the energy generated can be considered as renewable and is thus subsidized in some European countries. Analogously, CO(2) emissions of waste incinerators are only partly accounted for in greenhouse gas inventories. A novel approach for determining these fractions is the so-called balance method. In the present study, the implementation of the balance method on a waste-to-energy plant using oxygen-enriched combustion air was investigated. The findings of the 4-year application indicate on the one hand the general applicability and robustness of the method, and on the other hand the importance of reliable monitoring data. In particular, measured volume flows of the flue gas and the oxygen-enriched combustion air as well as corresponding O(2) and CO(2) contents should regularly be validated. The fraction of renewable (biogenic) energy generated throughout the investigated period amounted to between 27 and 66% for weekly averages, thereby denoting the variation in waste composition over time. The average emission factor of the plant was approximately 45 g CO(2) MJ(-1) energy input or 450 g CO(2) kg(-1) waste incinerated. The maximum error of the final result was about 16% (relative error), which was well above the error (<8%) of the balance method for plants with conventional oxygen supply.
城市固体废物和商业废物的热能利用在欧洲废物管理中变得越来越重要。由于废物材料通常由化石和生物基材料组成,因此产生的部分能源可以被认为是可再生的,因此在一些欧洲国家得到补贴。类似地,废物焚烧厂的 CO2 排放仅部分计入温室气体清单。确定这些分数的一种新方法是所谓的平衡法。本研究调查了在使用富氧燃烧空气的废物能源工厂中实施平衡法的情况。4 年应用的结果一方面表明了该方法的普遍适用性和稳健性,另一方面表明了可靠监测数据的重要性。特别是,烟气和富氧燃烧空气的测量体积流量以及相应的 O2 和 CO2 含量应定期进行验证。在所研究的时间段内,可再生(生物基)能源的产生比例在每周平均值上为 27%至 66%,从而表示了随着时间的推移废物成分的变化。该工厂的平均排放因子约为 45 g CO2 MJ(-1) 能源输入或 450 g CO2 kg(-1) 焚烧废物。最终结果的最大误差约为 16%(相对误差),明显高于具有传统供氧的工厂中平衡法的误差(<8%)。