Department of Chemistry and Applied Biosciences, ETH Zürich, Wolfgang-Pauli-Strasse 10, CH-8093 Zurich, Switzerland.
J Am Chem Soc. 2011 Mar 30;133(12):4216-9. doi: 10.1021/ja110834j. Epub 2011 Mar 8.
One-dimensional coordination polymer nanostructures are an emerging class of nanoscale materials with many potential applications. Here, we report the first case of coordination polymer nanofibers assembled using microfluidic technologies. Unlike common synthetic procedures, this approach enables parallel synthesis with an unprecedented level of control over the coordination pathway and facilitates the formation of 1D coordination polymer assemblies at the nanometer length scale. Finally, these nanostructures, which are not easily constructed with traditional methods, can be used for various applications, for example as templates to grow and organize functional inorganic nanoparticles.
一维配位聚合物纳米结构是一类新兴的纳米材料,具有许多潜在的应用。在这里,我们报告了首例使用微流控技术组装的配位聚合物纳米纤维。与常见的合成方法不同,这种方法能够以前所未有的协调途径控制水平进行并行合成,并促进在纳米长度尺度上形成 1D 配位聚合物组装。最后,这些用传统方法不易构建的纳米结构可用于各种应用,例如作为模板来生长和组织功能性无机纳米粒子。