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通过受限组装实现单晶配位聚合物纳米结构的最新进展。

Recent advances in nanoarchitectures of monocrystalline coordination polymers through confined assembly.

作者信息

Xia Lingling, Wang Qinyue, Hu Ming

机构信息

Engineering Research Center for Nanophotonics and Advanced Instrument (MOE), School of Physics and Electronic Science, East China Normal University, Shanghai 200241, China.

出版信息

Beilstein J Nanotechnol. 2022 Aug 12;13:763-777. doi: 10.3762/bjnano.13.67. eCollection 2022.

DOI:10.3762/bjnano.13.67
PMID:36051312
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9379653/
Abstract

Various kinds of monocrystalline coordination polymers are available thanks to the rapid development of related synthetic strategies. The intrinsic properties of coordination polymers have been carefully investigated on the basis of the available monocrystalline samples. Regarding the great potential of coordination polymers in various fields, it becomes important to tailor the properties of coordination polymers to meet practical requirements, which sometimes cannot be achieved through molecular/crystal engineering. Nanoarchitectonics offer unique opportunities to manipulate the properties of materials through integration of the monocrystalline building blocks with other components. Recently, nanoarchitectonics has started to play a significant role in the field of coordination polymers. In this short review, we summarize recent advances in nanoarchitectures based on monocrystalline coordination polymers that are formed through confined assembly. We first discuss the crystallization of coordination polymer single crystals inside confined liquid networks or on substrates through assembly of nodes and ligands. Then, we discuss assembly of preformed coordination polymer single crystals inside confined liquid networks or on substrates. In each part, we discuss the properties of the coordination polymer single crystals as well as their performance in energy, environmental, and biomedical applications.

摘要

由于相关合成策略的迅速发展，各种单晶配位聚合物得以问世。基于现有的单晶样品，人们对配位聚合物的内在性质进行了深入研究。鉴于配位聚合物在各个领域的巨大潜力，根据实际需求定制配位聚合物的性质变得尤为重要，而这有时无法通过分子/晶体工程实现。纳米结构学通过将单晶结构单元与其他组分整合，为调控材料性质提供了独特的机会。近年来，纳米结构学已开始在配位聚合物领域发挥重要作用。在这篇简短的综述中，我们总结了基于通过受限组装形成的单晶配位聚合物的纳米结构的最新进展。我们首先讨论通过节点和配体的组装在受限液体网络内部或在基底上配位聚合物单晶的结晶过程。然后，我们讨论预先形成的配位聚合物单晶在受限液体网络内部或在基底上的组装。在每个部分中，我们都讨论了配位聚合物单晶的性质及其在能源、环境和生物医学应用中的性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1609/9379653/d05be64b34a4/Beilstein_J_Nanotechnol-13-763-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1609/9379653/6c8ddcb02368/Beilstein_J_Nanotechnol-13-763-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1609/9379653/05fa1545a8b6/Beilstein_J_Nanotechnol-13-763-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1609/9379653/e80378db3727/Beilstein_J_Nanotechnol-13-763-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1609/9379653/7bf0c68452f7/Beilstein_J_Nanotechnol-13-763-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1609/9379653/2304f8f6e01b/Beilstein_J_Nanotechnol-13-763-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1609/9379653/18ec1a2f95ac/Beilstein_J_Nanotechnol-13-763-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1609/9379653/5512e9ec45ad/Beilstein_J_Nanotechnol-13-763-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1609/9379653/0fea4fa66659/Beilstein_J_Nanotechnol-13-763-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1609/9379653/d05be64b34a4/Beilstein_J_Nanotechnol-13-763-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1609/9379653/6c8ddcb02368/Beilstein_J_Nanotechnol-13-763-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1609/9379653/05fa1545a8b6/Beilstein_J_Nanotechnol-13-763-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1609/9379653/e80378db3727/Beilstein_J_Nanotechnol-13-763-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1609/9379653/7bf0c68452f7/Beilstein_J_Nanotechnol-13-763-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1609/9379653/2304f8f6e01b/Beilstein_J_Nanotechnol-13-763-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1609/9379653/18ec1a2f95ac/Beilstein_J_Nanotechnol-13-763-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1609/9379653/5512e9ec45ad/Beilstein_J_Nanotechnol-13-763-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1609/9379653/0fea4fa66659/Beilstein_J_Nanotechnol-13-763-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1609/9379653/d05be64b34a4/Beilstein_J_Nanotechnol-13-763-g010.jpg

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