Field dependence of temperature induced irreversible transformations of magnetic phases in Pr(0.5)Ca(0.5)Mn(0.975)Al(0.025)O(3) crystalline oxide.

Glass-like arrest has recently been reported in various magnetic materials. As in structural glasses, the kinetics of a first order transformation is arrested while retaining the higher entropy phase as a non-ergodic state. We show visual mesoscopic evidence of the irreversible transformation of the arrested antiferromagnetic-insulating phase in Pr(0.5)Ca(0.5)Mn(0.975)Al(0.025)O(3) to its equilibrium ferromagnetic-metallic phase with an isothermal increase of magnetic field, similar to its iso-field transformation on warming. The magnetic field dependence of the non-equilibrium to equilibrium transformation temperature is shown to be governed by Le Chatelier's principle.