Catalytic hydrodefluorination of pentafluorobenzene by [Ru(NHC)(PPh3)2(CO)H2]: a nucleophilic attack by a metal-bound hydride ligand explains an unusual ortho-regioselectivity.
作者信息
Panetier Julien A, Macgregor Stuart A, Whittlesey Michael K
机构信息
School of EPS, Chemistry, Heriot-Watt University, Edinburgh, UK.
出版信息
Angew Chem Int Ed Engl. 2011 Mar 14;50(12):2783-6. doi: 10.1002/anie.201006789. Epub 2011 Feb 17.