快速构建[5-6-7]三环骨架的紫堇菲灵碱 daphnilongeranin B。
Rapid construction of [5-6-7] tricyclic ring skeleton of Calyciphylline alkaloid daphnilongeranin B.
机构信息
Laboratory of Chemical Genomics, Shenzhen Graduate School of Peking University, Shenzhen University Town, Nanshan District, Shenzhen, China 518055.
出版信息
Org Lett. 2011 Apr 1;13(7):1812-5. doi: 10.1021/ol200312q. Epub 2011 Mar 9.
PMID:21388118
Abstract
A concise photochemical [2 + 2] cycloaddition-Grob fragmentation sequence sets the common tricyclic ring skeletons of the Calyciphylline A-type alkaloids, particularly those in daphnilongeranins, daphniyunnines, and daphniglaucins.
摘要
一个简洁的光化学 [2 + 2] 环加成-格罗卜碎裂序列设定了 Calyciphylline A 型生物碱的共同三环骨架，特别是那些在 daphnilongeranins、daphniyunnines 和 daphniglaucins 中的骨架。
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