Laboratoire CRISMAT, CNRS UMR 6508, ENSICAEN, Caen, France.
J Phys Condens Matter. 2010 Nov 10;22(44):445901. doi: 10.1088/0953-8984/22/44/445901. Epub 2010 Oct 22.
Dielectric and magnetodielectric peaks have been evidenced by ε(T, H) measurements in spin induced ferroelectrics: CuCrO(2) and AgCrO(2) delafossites. Such behaviour, also found in several other improper ferroelectrics, can be explained in the frame of Landau analysis of phase transitions with two coupled order parameters: antiferromagnetic ordered moment, L, and polarization, P. The existence of such anomalies in the dielectric constant observed at T(N) is very general. The existence of this peak is not due to any linear coupling term between P and L in this system, but rather due to the L(2)P(2) term which always exists in every compound, whatever the symmetry/space group is.
通过对自旋诱导铁电体 CuCrO(2) 和 AgCrO(2) 德拉弗斯石的 ε(T, H) 测量,发现了介电和磁介电峰。这种行为也在其他几种不合适的铁电体中发现,可以用朗道相变分析来解释,该分析有两个耦合的序参量:反铁磁有序矩 L 和极化 P。在 T(N) 处观察到介电常数中的这种异常现象非常普遍。这种峰值的存在不是由于系统中 P 和 L 之间存在任何线性耦合项,而是由于 L(2)P(2)项总是存在于每个化合物中,无论其对称/空间群如何。