揭示固相上硫代点击反应的本质。
Revealing the nature of thio-click reactions on the solid phase.
机构信息
Department of Organic Chemistry, Polymer Chemistry Research Group, Ghent University, Krijgslaan 281 S4-bis, B-9000 Ghent, Belgium.
出版信息
Chem Commun (Camb). 2011 Apr 28;47(16):4652-4. doi: 10.1039/c0cc05340f. Epub 2011 Mar 21.
PMID:21423975
Abstract
Thiol- and yne-functionalized beads were manufactured in a simple microfluidic setup. While CuAAC and thiol-yne reactions were performed on yne-functionalized beads, 9 different thiol-X reactions were compared, in terms of kinetics and conversion, on thiol-functionalized beads.
摘要
巯基和炔基功能化珠子是在简单的微流控装置中制造的。当炔基功能化珠子上进行 CuAAC 和巯基-炔反应时，比较了 9 种不同的巯基-X 反应在巯基功能化珠子上的动力学和转化率。
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