School of Chemistry, The Sackler Faculty of Exact Sciences, Tel Aviv University, Ramat Aviv 69978, Tel Aviv, Israel.
Chem Commun (Camb). 2011 May 21;47(19):5368-75. doi: 10.1039/c1cc10150a. Epub 2011 Mar 24.
Basic research in the chemistry of hexameric resorcin[4]arenes and pyrogallol[4]arenes during the last decade is reviewed. Applications of NMR methods to determine solution structures, host guest properties and exchange dynamics are discussed. The scientific issue is the behavior of molecules in small spaces; the challenge is to translate this information to practical applications in, say, catalysis or transport.
回顾了过去十年中六聚体间苯二酚[4]芳烃和焦倍酚[4]芳烃化学的基础研究。讨论了 NMR 方法在确定溶液结构、主体客体性质和交换动力学方面的应用。科学问题是分子在小空间中的行为；挑战是将这些信息转化为实际应用，例如在催化或传输方面的应用。
