从非手性前体制备手性多孔材料的超声热诱导合成。

Induction in urothermal synthesis of chiral porous materials from achiral precursors.

机构信息

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, Fuzhou, Fujian 350002, PR China.

出版信息

Chem Commun (Camb). 2011 May 7;47(17):4950-2. doi: 10.1039/c1cc10486a. Epub 2011 Mar 25.

DOI:10.1039/c1cc10486a

PMID:21442101

Abstract

Special asymmetric crystallization of porous framework materials from achiral precursors under urothermal conditions is successfully achieved by using an enantiopure liquid as a co-solvent and chirality induction agent, which provides a new strategy for the synthesis of homochiral porous materials containing only achiral building blocks.

摘要

在手性溶剂和手性诱导剂的辅助下，成功地实现了非手性前体制备的多孔骨架材料的特殊不对称结晶，为合成仅包含非手性构筑单元的同手性多孔材料提供了新策略。