“柱撑”策略与手性诱导相结合：一种从非手性前体制备纯手性三维配位聚合物的方法。
A combination of the "pillaring" strategy and chiral induction: an approach to prepare homochiral three-dimensional coordination polymers from achiral precursors.
作者信息
Wen Yuehong, Sheng Tianlu, Sun Zhihao, Xue Zhenzhen, Wang Yanlong, Wang Yong, Hu Shengmin, Ma Xiao, Wu Xintao
机构信息
State key Laboratory of Structure Chemistry Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, China.
出版信息
Chem Commun (Camb). 2014 Aug 7;50(61):8320-3. doi: 10.1039/c4cc03478c.
Utilizing enantiopure camphorsulfonic acid as a chiral induction agent, 3D homochiral complexes were obtained from achiral 2D layers and MoO4(2-) pillars. This methodology combines the "pillaring" strategy with chiral induction, providing a new way to synthesize homochiral 3D coordination polymers intentionally from achiral precursors.
利用对映体纯的樟脑磺酸作为手性诱导剂，从非手性的二维层和MoO4(2-)柱获得了三维同手性配合物。该方法将“柱撑”策略与手性诱导相结合，为从非手性前体有意合成同手性三维配位聚合物提供了一种新方法。
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