Kumar Shalendra, Kim Geun Woo, Koo B H, Sharma S K, Knobel M, Chung Hanshik, Lee Chan Gyu
School of Nano and Advanced Materials Engineering, Changwon National University, 9 Sarim-Dong, Changwon 641-773, Republic of Korea.
J Nanosci Nanotechnol. 2011 Jan;11(1):555-9. doi: 10.1166/jnn.2011.3176.
This paper reports the effect of Fe doping on the structure and room temperature ferromagnetism of CeO2 nanoparticles. X-ray diffraction and the selective area electron diffraction measurements performed on the Ce(1-x)Fe(x)O2 (0 < or = x < or = 0.07) nanoparticles showed a single-phase nature with a cubic structure, and none of the samples showed the presence of any secondary phase. The mean particle size, which was calculated using transmission electron microscopy, increased with the increase in the Fe content. The DC magnetization measurements that were performed at room temperature showed that all the samples exhibited ferromagnetism. The saturation magnetic moment increased with the increase in the Fe content.
本文报道了铁掺杂对二氧化铈纳米颗粒结构和室温铁磁性的影响。对Ce(1-x)Fe(x)O2(0≤x≤0.07)纳米颗粒进行的X射线衍射和选区电子衍射测量表明其具有立方结构的单相性质,且所有样品均未显示出任何第二相的存在。使用透射电子显微镜计算得出的平均粒径随铁含量的增加而增大。在室温下进行的直流磁化测量表明,所有样品均表现出铁磁性。饱和磁矩随铁含量的增加而增大。