利用天然阳光和空气进行苄基卤化物的有氧氧化。
Utilization of natural sunlight and air in the aerobic oxidation of benzyl halides.
机构信息
State Key Laboratory of Natural and Biomimetic Drugs, School of Pharmaceutical Sciences, Peking University, Xue Yuan Road 38, Beijing 100191, China.
出版信息
Org Lett. 2011 May 6;13(9):2168-71. doi: 10.1021/ol2002013. Epub 2011 Mar 29.
PMID:21446682
Abstract
A novel, efficient oxidation of α-aryl halogen derivatives to the corresponding α-aryl carbonyl compounds at room temperature has been disclosed. Natural sunlight and air are successfully utilized in this approach through the combination of photocatalysis and organocatalysis. A plausible mechanism was proposed on the basis of the mechanistic studies.
摘要
本文报道了一种在室温下将α-芳基卤代物高效氧化为相应α-芳基羰基化合物的新方法。该方法通过光催化和有机催化的结合，成功地利用了自然光和空气。基于机理研究提出了一个合理的反应机制。
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