State Key Laboratory of Applied Organic Chemistry, Department of Chemistry, Lanzhou University, Lanzhou, 730000, PR China.
Org Lett. 2011 May 6;13(9):2302-5. doi: 10.1021/ol2005616. Epub 2011 Apr 1.
First total syntheses of the isoechinulin-type alkaloids: Tardioxopiperazine A, Isoechinulin A, and Variecolorin C have been achieved from a common key intermediate 5, which was derived from a regiocontrolled Stille cross-coupling reaction of an allylindium reagent.
Tardioxopiperazine A、Isoechinulin A 和 Variecolorin C 是从一个共同的关键中间体 5 实现的,该中间体是通过区域控制的烯丙基铟试剂的 Stille 交叉偶联反应得到的。