测定乙腈中各种醛酮的氢化物亲和力。
Determination of hydride affinities of various aldehydes and ketones in acetonitrile.
机构信息
The State Key Laboratory of Elemento-Organic Chemistry, Department of Chemistry, Nankai University, Tianjin 300071, PR China.
出版信息
Org Lett. 2011 May 6;13(9):2456-9. doi: 10.1021/ol2006488. Epub 2011 Apr 1.
PMID:21456587
Abstract
The hydride affinities of 21 typical aldehydes and ketones in acetonitrile were determined by using an experimental method, which is valuable for chemists choosing suitable reducing agents to reduce them. The focus of this paper is to introduce a very facile experimental method, which can be used to determine the hydride affinities of various carbonyl compounds in solution.
摘要
采用实验方法测定了 21 种典型醛酮在乙腈中的氢化物亲和力，这对于化学家选择合适的还原剂将其还原具有重要价值。本文的重点是介绍一种非常简便的实验方法，可用于测定溶液中各种羰基化合物的氢化物亲和力。
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