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基于香豆素席夫碱部分的 Na+ 触发荧光传感器用于检测 Mg2+。

Na+ triggered fluorescence sensors for Mg2+ detection based on a coumarin salen moiety.

机构信息

Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China.

出版信息

Org Lett. 2011 May 6;13(9):2252-5. doi: 10.1021/ol200530g. Epub 2011 Apr 5.

Abstract

Two coumarin salen-based sensors CS1 and CS2 can exhibit a pronounced fluorescence enhancement response toward Mg(2+) as high as 36-fold (CS1) and 111-fold (CS2) in the presence of Na(+) as a synergic trigger. More importantly, the fluorescent color of CS1 was bright green instead of weak yellow after the addition of Mg(2+) and Na(+) together, which can be easily detected by the naked eye.

摘要

两种香豆素水杨醛席夫碱传感器 CS1 和 CS2 在钠离子作为协同触发剂存在的情况下,对镁离子表现出高达 36 倍(CS1)和 111 倍(CS2)的显著荧光增强响应。更重要的是,CS1 的荧光颜色在加入镁离子和钠离子后变为亮绿色而不是微弱的黄色,这可以通过肉眼轻松检测到。

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