Key Laboratory of Materials for High Power Lasers, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China.
Opt Lett. 2011 Apr 1;36(7):1173-5. doi: 10.1364/OL.36.001173.
A novel Er(3+)/Pr(3+) codoped germanate glass was fabricated and analyzed. Efficient emission at 2.7 μm from the glass was observed upon excitation of a conventional 980 nm laser diode. The 2.7 μm emission characteristics and energy transfer (ET) were investigated. Population inversions between ⁴I(13/2) and ⁴I(11/2) levels have been achieved, and an enhanced emission from 2550 to 2800 nm was obtained. Large ET efficiency of 95% indicates that the ET process from Er(3+) to Pr(3+) (⁴I(13/2), ³H₄)→(⁴I(15/2), ³F₃) is efficient and that Pr(3+) can enhance the emission of 2.7 μm by quenching the lower laser level of Er(3+) via ET.
一种新型的掺铒/掺镨锗酸盐玻璃被制备和分析。在激发传统的 980nm 激光二极管后,观察到玻璃在 2.7μm 处的有效发射。研究了 2.7μm 的发射特性和能量传递(ET)。已经实现了 ⁴I(13/2)和 ⁴I(11/2)能级之间的粒子数反转,并且获得了从 2550nm 到 2800nm 的增强发射。高达 95%的大 ET 效率表明,从 Er(3+)到 Pr(3+)(⁴I(13/2),³H₄)→(⁴I(15/2),³F₃)的 ET 过程是有效的,并且 Pr(3+)可以通过 ET 猝灭 Er(3+)的较低激光能级来增强 2.7μm 的发射。