Department of Chemistry, Tokyo Gakugei University, Tokyo, 184-8501, Japan.
Nanoscale. 2011 Jun;3(6):2421-9. doi: 10.1039/c0nr00968g. Epub 2011 Apr 11.
Since the first discovery of fullerenes in 1985, the insertion of one or more atoms into a hollow fullerene cage has been attempted. Furthermore, synthesis and extraction of metallofullerene, La@C(n), were reported in 1991. Recent successful isolation and purification of metallofullerenes have facilitated the investigation of their chemical properties. This mini-review presents a summary of the recent progress of chemical functionalization and supramolecular chemistry of M@C(82). Selective functionalization and successful structural analysis of derivatives have revealed their chemical features arising from endohedral metal doping.
自 1985 年首次发现富勒烯以来，人们一直试图将一个或多个原子插入富勒烯笼中。此外，1991 年还报道了金属富勒烯 La@C(n)的合成和提取。最近金属富勒烯的成功分离和纯化促进了对其化学性质的研究。这篇迷你综述总结了 M@C(82)的化学功能化和超分子化学的最新进展。对衍生物的选择性功能化和成功的结构分析揭示了它们由于内配位金属掺杂而产生的化学特性。
