Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University, Tsushima, Okayama 700-8530, Japan.
Chem Commun (Camb). 2011 Jun 7;47(21):6090-2. doi: 10.1039/c1cc11572c. Epub 2011 Apr 11.
Chiral diporphyrin receptor 1, which has a macrocyclic cavity to sandwich aromatic guest molecules via double π-π stacking interactions, enabled the naked-eye detection of an aromatic explosive as well as chiral discrimination in NMR.
手性二卟啉受体 1 具有大环腔,可以通过双重 π-π 堆积相互作用将芳香客体分子夹在中间,从而实现了对芳香爆炸物的肉眼检测以及 NMR 中的手性识别。