Center for Nanoscale Materials, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois 60439, USA.
Nanoscale. 2011 May;3(5):2247-55. doi: 10.1039/c1nr10153f. Epub 2011 Apr 11.
Silver (Ag) nanowires with chemically clean surfaces have been directly grown on semi-insulating gallium arsenide (GaAs) wafers through a simple solution/solid interfacial reaction (SSIR) between the GaAs wafers themselves and aqueous solutions of silver nitrate (AgNO(3)) at room temperature. The success in synthesis of Ag nanowires mainly benefits from the low concentration of surface electrons in the semi-insulating GaAs wafers that can lead to the formation of a low-density of nuclei that facilitate their anisotropic growth into nanowires. The resulting Ag nanowires exhibit rough surfaces and reasonably good electric conductivity. These characteristics are beneficial to sensing applications based on single-nanowire surface-enhanced Raman scattering (SERS) and possible surface-adsorption-induced conductivity variation.
通过半绝缘砷化镓(GaAs)晶片自身与硝酸银(AgNO3)水溶液在室温下的简单溶液/固界面反应(SSIR),可直接在半绝缘 GaAs 晶片上生长出具有化学清洁表面的银纳米线。Ag 纳米线合成的成功主要得益于半绝缘 GaAs 晶片表面电子浓度低,这有利于形成低密度的核,从而促进其各向异性生长成纳米线。所得的 Ag 纳米线具有粗糙的表面和相当好的导电性。这些特性有利于基于单纳米线表面增强拉曼散射(SERS)的传感应用和可能的表面吸附诱导的电导率变化。