Photosciences and Photonics Section, Chemical Sciences and Technology Division, National Institute for Interdisciplinary Science and Technology (CSIR), Thiruvananthapuram-695 019, Kerala, India.
Org Lett. 2011 May 6;13(9):2498-501. doi: 10.1021/ol200668a. Epub 2011 Apr 12.
Synthesis, spectral, and single-crystal X-ray structural analysis of meso-aryl triphyrin(2.1.1) featuring three pyrrole rings and four meso-aryl rings are described. The title compound represents the first example of a ring-contractedmeso-aryl β-unsubstituted free-base triphyrin containing only pyrrole rings reported to date and generates 2-D supramolecular assembly in the solid state.
中-芳基三卟啉(2.1.1)的合成、光谱和单晶 X 射线结构分析,其特征在于三个吡咯环和四个中-芳基环。标题化合物代表迄今为止报道的第一个仅含吡咯环的环缩合中-芳基β-未取代游离碱三卟啉的实例,并在固态中生成 2-D 超分子组装。