四氯（吡啶-2-羧酸根-κN，O）（三乙铵）锡（IV）
Triethyl-ammonium tetra-chlorido(pyridine-2-carboxyl-ato-κN,O)stannate(IV).
作者信息
Najafi Ezzatollah, Amini Mostafa M, Ng Seik Weng
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Feb 19;67(Pt 3):m351. doi: 10.1107/S1600536811005460.
Abstract
The cation and the anion in the title salt, (C(6)H(16)N)[SnCl(4)(C(6)H(4)NO(2))], are linked by an N-H⋯O hydrogen bond. The Sn(IV) atom in the stannate anion is chelated by the pyridine-2-carboxyl-ate group and exists in a cis-SnCl(4)NO octa-hedral geometry. The cation is disordered over two positions in a 0.564 (1):0.436 (1) ratio.
摘要
标题盐（C(6)H(16)N)[SnCl(4)(C(6)H(4)NO(2))]中的阳离子和阴离子通过N-H⋯O氢键相连。锡酸根阴离子中的Sn(IV)原子被吡啶-2-羧酸根基团螯合，呈顺式-SnCl(4)NO八面体几何构型。阳离子在两个位置上无序排列，比例为0.564 (1):0.436 (1)。
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