Cho-Schultz Sujin, Kath John C, Moore Curtis, Rheingold Arnold L, Yanovsky Alex
Acta Crystallogr Sect E Struct Rep Online. 2011 Feb 19;67(Pt 3):o650. doi: 10.1107/S1600536811005332.
The title compound, C(14)H(13)BrN(2)O, was obtained by reaction of indan-1-yl methane-sulfonate with 2-amino-5-bromo-pyridin-3-ol in the presence of caesium carbonate. The indane ring system is approximately planar [all but one of the C atoms are coplanar within 0.03 Å, the latter atom being displaced by 0.206 (2) Å from the mean plane through the remaining atoms] and forms a dihedral angle of 58.41 (4)° with the pyridine ring. In the crystal, centrosymmetrically related mol-ecules are linked into dimers by N-H⋯N hydrogen bonds.
标题化合物C(14)H(13)BrN(2)O是通过茚满-1-基甲磺酸盐与2-氨基-5-溴吡啶-3-醇在碳酸铯存在下反应得到的。茚满环系近似平面[除一个碳原子外，所有碳原子在0.03 Å范围内共面，后者原子相对于通过其余原子的平均平面位移0.206 (2) Å]，并与吡啶环形成58.41 (4)°的二面角。在晶体中，中心对称相关的分子通过N-H⋯N氢键连接成二聚体。
