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2-溴-2-甲基-N-(4-硝基苯基)丙酰胺

2-Bromo-2-methyl-N-(4-nitro-phen-yl)propanamide.

作者信息

Moreno-Fuquen Rodolfo, Quintero David E, Zuluaga Fabio, Haiduke Roberto L A, Kennedy Alan R

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Feb 19;67(Pt 3):o659. doi: 10.1107/S1600536811005320.

DOI:10.1107/S1600536811005320
PMID:21522410
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3051943/
Abstract

The title compound, C(10)H(11)BrN(2)O(3), exhibits a small twist between the amide residue and benzene ring [the C-N-C-C torsion angle = 12.7 (4)°]. The crystal structure is stabilized by weak N-H⋯O, C-H⋯Br and C-H⋯O inter-actions. These lead to supra-molecular layers in the bc plane.

摘要

标题化合物C(10)H(11)BrN(2)O(3)中，酰胺残基与苯环之间存在小的扭曲[C-N-C-C扭转角 = 12.7 (4)°]。晶体结构通过弱的N-H⋯O、C-H⋯Br和C-H⋯O相互作用得以稳定。这些相互作用导致在bc平面上形成超分子层。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0fc7/3051943/5d25f244ab8a/e-67-0o659-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0fc7/3051943/f7322bbfe7b9/e-67-0o659-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0fc7/3051943/0ce53184e119/e-67-0o659-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0fc7/3051943/5d25f244ab8a/e-67-0o659-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0fc7/3051943/f7322bbfe7b9/e-67-0o659-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0fc7/3051943/0ce53184e119/e-67-0o659-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0fc7/3051943/5d25f244ab8a/e-67-0o659-fig3.jpg

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