Suleiman Gwaram Nura, Ikmal Hisham Nurul Azimah, Khaledi Hamid, Mohd Ali Hapipah
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 24;67(Pt 1):m108. doi: 10.1107/S1600536810052578.
In the title compound, [Ni(NCS)(2)(C(13)H(19)N(3)O)(H(2)O)], the Ni(II) ion is six-coordinated by the N,N',N''-tridentate Schiff base, the N atoms of two thio-cyanate ligands and one water O atom in a distorted octa-hedral geometry. Intra-molecular C-H⋯N and C-H⋯O hydrogen bonds occur. In the crystal, O-H⋯S, O-H⋯O and C-H⋯S hydrogen bonds link adjacent mol-ecules into layers parallel to the ac plane.
在标题化合物[Ni(NCS)₂(C₁₃H₁₉N₃O)(H₂O)]中，Ni(II)离子由N,N',N''-三齿席夫碱、两个硫氰酸根配体的N原子和一个水分子的O原子以扭曲的八面体几何构型六配位。分子内存在C—H⋯N和C—H⋯O氢键。在晶体中，O—H⋯S、O—H⋯O和C—H⋯S氢键将相邻分子连接成平行于ac平面的层。
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